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  • 标题:Effect of carbonates/phosphates as nucleophilic catalysts in dimethylformamide for efficient cyanosilylation of aldehydes and ketones
  • 本地全文:下载
  • 作者:G. K. Surya Prakash ; Habiba Vaghoo ; Chiradeep Panja
  • 期刊名称:Proceedings of the National Academy of Sciences
  • 印刷版ISSN:0027-8424
  • 电子版ISSN:1091-6490
  • 出版年度:2007
  • 卷号:104
  • 期号:9
  • 页码:3026-3030
  • DOI:10.1073/pnas.0611309104
  • 语种:English
  • 出版社:The National Academy of Sciences of the United States of America
  • 摘要:Cyanosilylation of aldehydes and aliphatic ketones can be carried out in dimethylformamide even without the use of any catalyst. In the presence of nucleophilic catalysts such as carbonate and phosphate salts, the reaction rate is significantly enhanced.
  • 关键词:nature of solvent
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