文章基本信息

标题：Effect of carbonates/phosphates as nucleophilic catalysts in dimethylformamide for efficient cyanosilylation of aldehydes and ketones
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作者：G. K. Surya Prakash ; Habiba Vaghoo ; Chiradeep Panja 等
期刊名称：Proceedings of the National Academy of Sciences
印刷版ISSN：0027-8424
电子版ISSN：1091-6490
出版年度：2007
卷号：104
期号：9
页码：3026-3030
DOI：10.1073/pnas.0611309104
语种：English
出版社：The National Academy of Sciences of the United States of America
摘要：Cyanosilylation of aldehydes and aliphatic ketones can be carried out in dimethylformamide even without the use of any catalyst. In the presence of nucleophilic catalysts such as carbonate and phosphate salts, the reaction rate is significantly enhanced.
关键词：nature of solvent