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  • 标题:Directly patternable, highly conducting polymers for broad applications in organic electronics
  • 本地全文:下载
  • 作者:Joung Eun Yoo ; Kwang Seok Lee ; Andres Garcia
  • 期刊名称:Proceedings of the National Academy of Sciences
  • 印刷版ISSN:0027-8424
  • 电子版ISSN:1091-6490
  • 出版年度:2010
  • 卷号:107
  • 期号:13
  • 页码:5712-5717
  • DOI:10.1073/pnas.0913879107
  • 语种:English
  • 出版社:The National Academy of Sciences of the United States of America
  • 摘要:Postdeposition solvent annealing of water-dispersible conducting polymers induces dramatic structural rearrangement and improves electrical conductivities by more than two orders of magnitude. We attain electrical conductivities in excess of 50 S/cm when polyaniline films are exposed to dichloroacetic acid. Subjecting commercially available poly(ethylene dioxythiophene) to the same treatment yields a conductivity as high as 250 S/cm. This process has enabled the wide incorporation of conducting polymers in organic electronics; conducting polymers that are not typically processable can now be deposited from solution and their conductivities subsequently enhanced to practical levels via a simple and straightforward solvent annealing process. The treated conducting polymers are thus promising alternatives for metals as source and drain electrodes in organic thin-film transistors as well as for transparent metal oxide conductors as anodes in organic solar cells and light-emitting diodes.
  • 关键词:electrical conductivity ; solar cells ; thin-film transistors ; light-emitting diodes ; polyaniline
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