文章基本信息

标题：Modeling and analytical simulation of anterior polymerization in the presence of an inert material
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作者：A.M. Jimada ; R.O. Olayiwola ; M.D. Shehu 等
期刊名称：Journal of Applied Sciences and Environmental Management
印刷版ISSN：1119-8362
出版年度：2017
卷号：21
期号：1
页码：101-109
出版社：Department of Pure & Industrial Chemistry, University of Port Harcourt
摘要：The ability to fabricate advanced materials with specific properties efficiently requires a complete understanding of the polymerization kinetics and the effect of several preparative variables such as temperature, monomer and initiator. This paper presents an analytical method for describing anterior polymerization in two adjacent thin layers. Both the initial temperatures and initial monomer and initiator concentrations are assumed to depend on the space variable. We prove the existence and uniqueness of solution of the model by actual solution method. The equations are solved using parameter-expanding method and eigenfunctions expansion technique. The results obtained were discussed. The study shows that the Frank-Kamenetskii number and frequency factors of the two reactions have significant effects on the propagation of the polymerization wave. Keywords: Polymerization, anterior polymerization, polymers, Arrhenius kinetics, parameter-expanding method, eigenfunctions expansion technique
关键词：Polymerization, anterior polymerization, polymers, Arrhenius kinetics, parameter-expanding method, eigenfunctions expansion technique