文章基本信息

标题：ガスクロマトグラフィーによる食品中の9種トリアジン系除草剤の同時分析法
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作者：外海泰秀 ; 長谷川ゆかり ; 中村優美子等
期刊名称：Journal of Health Science
印刷版ISSN：1344-9702
电子版ISSN：1347-5207
出版年度：1988
卷号：34
期号：5
页码：421-429
DOI：10.1248/jhs1956.34.421
出版社：The Pharmaceutical Society of Japan
摘要：Simultaneous determination of nine kinds of triazine herbicides was described. The pesticides were extracted from the sample with acetone, diluted with 10% NaCl solution, and re-extracted with dichloromethane. The organic layer was concentrated and purified with Florisil column chromatography. Nine pesticides on the column were quantitatively recovered with 100 ml of ethyl ether-ethyl acetate (1 : 1) mixture solution after washing with 50 ml of hexane-ether (1 : 1) mixture solution. The eluate was concentrated and determined with a flame thermionic detector by gas chromatography. Recoveries of nine pesticides (prometone, propazine, atrazine, simazine, prometryn, ametryn, simetryn, dimethametryn, metribuzin) added to carrot, orange, soy bean and unpolished-rice at 0.5 ppm were within the range of 62.4-92.6%. The detection limit for each pesticide in the sample by the proposed method was 0.05 ppm.
关键词：pesticide;triazine herbicide;GC;flame thermionic detector;florisil column chromatography;hexane-acetonitrile partition;Ultrabond 20 M;soy bean