文章基本信息

标题：ガスクロマトグラフィー用内部標準物質1,1,1,2-テトラクロロエタンの分解について
本地全文：下载
作者：溝渕膺彦 ; 奥田三郎 ; 西川喜孝等
期刊名称：Journal of Health Science
印刷版ISSN：1344-9702
电子版ISSN：1347-5207
出版年度：1987
卷号：33
期号：3
页码：165-169
DOI：10.1248/jhs1956.33.165
出版社：The Pharmaceutical Society of Japan
摘要：A compound of 1, 1, 1, 2-tetrachloroethylene (TET) is used as an inner standard for the determination of trichloroethylene (TRI) and tetrachloroethylene (PER) in detergents used for keeping toilet clean by headspace-gas chromatography. As small peaks appeared near at the retention time of TRI under alkaline solution, however, compounds decomposed from the inner standard solution were investigated. Main compounds, which were produced by the decomposition of the TET, were only TRI under alkaline solution, and chloroform and TRI under alkaline solution with solution hypochloride, and two unknown compounds at the retention times of 1.1 and 1.5 min under acidic conditions with phosphoric acid and sodium hypochloride. According to the regression equation between molecular weight and retention times and the comparison of their retention times with those of each standard, they were identified as methyl chloride and 1, 1-dichloroethylene, respectively.
关键词：decomposition;1, 1, 1, 2-tetrachloroethane;chloroform;trichloroethylene;methyl chloride;1, 1-dichloroethylene;alkaline condition;acidic condition;sodium hypochloride