文章基本信息

标题：Forensic Chemical Study on Nylon Fibers by Acid-Catalyzed Pyrolysis Gas Chromatography
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作者：YUZI TAKEKOSHI ; SUSUMU KANNO ; SHOZI KAWASE 等
期刊名称：Journal of Health Science
印刷版ISSN：1344-9702
电子版ISSN：1347-5207
出版年度：1996
卷号：42
期号：1
页码：28-31
DOI：10.1248/jhs1956.42.28
出版社：The Pharmaceutical Society of Japan
摘要：We developed a method for forensic identification of minute fibers of 6-nylon and 6, 6-nylon by acid-catalyzed pyrolysis gas chromatography (PyGC). The fibers were pyrolyzed in the presence of phosphoric acid with a Curie point pyrolyzer directly connected to a gas chromatograph and a gas chromatograph/mass spectrometer. Phosphoric acid promoted production of specific volatile substances such as 3 isomers of hexenenitrile and ε-caprolactam from 6-nylon and adiponitrile from 6, 6-nylon. The phosphoric acid-catalyzed PyGC was able to identify a smaller amount of nylon fibers than the conventional non-catalyzed PyGC.
关键词：acid-catalyzed pyrolysis GC;6-nylon fiber;6, 6-nylon fiber;phosphoric acid;forensic identification