文章基本信息

标题：ディスクリートネブライゼイション : 亜酸化窒素 : アセチレンフレーム原子吸光法による健康飲料中のゲルマニウムの分析
本地全文：下载
作者：大島晴美 ; 斎藤勳 ; 河村典久等
期刊名称：Journal of Health Science
印刷版ISSN：1344-9702
电子版ISSN：1347-5207
出版年度：1990
卷号：36
期号：3
页码：219-225
DOI：10.1248/jhs1956.36.219
出版社：The Pharmaceutical Society of Japan
摘要：A simple and rapid method was developed for the analysis of total germanium (Ge), inorganic Ge (GeO₂) and organic Ge (β-carboxyethyl germanium oxide ; CE-Ge) in Ge-containing health beverages. In order to determine total Ge, the sample was digested with HNO₃. Ge in the sample was changed to inorganic Ge, and extracted with CCl₄ as chloride. The amount of Ge was determined by polarized Zeeman atomic absorption spectrometry with a nitrous oxide-acetylene flame by using the discrete nebulization technique (FZAAS). On the other hand, inorganic Ge and organic Ge in the sample were separated by organic solvent extraction and determined by FZAAS without acid digestion. Recoveries of Ge from juice fortified at the level of 25-250 μg Ge/g were more than 92%. The calibration graph was linear between 0.25 and 20μg Ge. The proposed method was recommended for the determination of Ge and differentiation of inorganic Ge and organic Ge in Ge-containing health beverages.
关键词：germanium;polarized Zeeman AAS;nitrous oxide-acetylene flame AAS;discrete nebulization technique;health beverage;β-carboxyethyl germanium oxide