文章基本信息

标题：チューインガム製品中の銅クロロフィル類似物質の構造
本地全文：下载
作者：大戸幹也 ; 山本敦 ; 松永明信等
期刊名称：Journal of Health Science
印刷版ISSN：1344-9702
电子版ISSN：1347-5207
出版年度：1994
卷号：40
期号：3
页码：279-285
DOI：10.1248/jhs1956.40.279
出版社：The Pharmaceutical Society of Japan
摘要：Multiple copper chlorophyll analogues were detected in the chewing gum product containing the copper chlorophyll dye using a HPLC apparatus with photodiode array detection. The main components among these analogues were assumed to be 10-hydroxy copper chlorophyll a and b by IR, FAB/mass and NMR spectrometry. Since these copper chlorophyll analogues were main components in the commercial food additive dye, "copper chlorophyll", it was clear that these analogues in the chewing gum product were carried over from this food additive. The 10-hydroxy pheophytins, which are precursors of these copper chlorophyll analogues, were detected from the extract of silkworm excreta, the original material of this dye. These copper chlorophyll analogues were possibly produced by the metalation reaction between the copper and the 10-hydroxy pheophytins which might be generated from the oxidation of pheophytins, like "allomerization reaction", during the process of the synthesis of the original material and its storage. It is possible that these analogues have already been the main components in the original dye.
关键词：chewing gum product;synthetic color;copper chlorophyll;copper chlorophyll analogue;pheophytin analogue