文章基本信息

标题：Studies on the Alkaloids of Menispermaceous Plants. CXXIII. Paper Chromatography of Oxyacanthine and Repandine
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作者：Masao Tomita ; Yasuo Inubushi ; Eiichi Fujita 等
期刊名称：Chemical and Pharmaceutical Bulletin
印刷版ISSN：0009-2363
电子版ISSN：1347-5223
出版年度：1955
卷号：3
期号：2
页码：97-99
DOI：10.1248/cpb1953.3.97
出版社：The Pharmaceutical Society of Japan
摘要：The purity and homogeneity of the sample of oxyacanthine showing m.p.210∼213° or 214∼216°(in vacuum), [α]²⁴_D : +276.1°(CHCl₃), employed in our previous work was examined by paper chromatography, etc. These techniques afforded no evidence that it was accompanied with its optical isomer, repandine. The conditions under which repandine may form from oxyacanthine by treatment with hydrogen chloride was also investigated using the same sample of oxyacanthine but furnished no evidence for tis contamination with repandine. As a result, it was established that the action of 1.12 moles of hydrogen chloride upon 1 mole of oxyacanthine invariably gave repandine.