文章基本信息

标题：高速液体クロマトグラフィーによる羊毛繊維中の防虫加工剤4,6-Dichloro-7-(2,4,5-trichlorophenoxy)-2-trifluoromethylbenzimidazole(DTTB)の定量法
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作者：萩原輝彦 ; 寺島潔 ; 奥本千代美等
期刊名称：Journal of Health Science
印刷版ISSN：1344-9702
电子版ISSN：1347-5207
出版年度：1982
卷号：28
期号：3
页码：155-159
DOI：10.1248/jhs1956.28.3_155
出版社：The Pharmaceutical Society of Japan
摘要：A method for the determination of 4, 6-dichloro-7-(2, 4, 5-trichlorophenoxy)-2-trifluoromethyl-benzimidazole (DTTB), which was used as a mothproofing agent in wool fabrics, was developed. DTTB was extracted with ether from 10% sodium hydroxide solution of wool fabrics, and the purification of the extracts was accomplished by silicagel column chromatography. The purified extracts were dissolved in methanol containing internal standard and then measured by reversed-phase high performance liquid chromatography on LiChrosolb RP-18. The solution of methanol-water-acetic acid (90 : 9 : 1) was used as the mobile phase and chrysene was used as an internal standard. Detection was accomplished with fluorescence spectrophotometer operated at λex=300 nm and λem=360 nm. Recoveries averaged 84.9% and 99.4% for the untreated carpet to which 2.3μg/g of DTTB was added and the processed fabrics treated with Mitin LA, which is the market products of DTTB, respectively.
关键词：4, 6-dichloro-7-(2, 4, 5-trichlorophenoxy)-2-trifluoromethylbenzimidazole;DTTB;Mitin LA;mothproofing agent;wool fabrics;fluorescence spectrophotometer;reversed-phase high performance liquid chromatography