文章基本信息

标题：食品中の残留農薬分析に関する研究(第36報)果実類中のフェノキシ系農薬(2,4-D, 2,4,5-Tおよび2,4,5-TP)の多成分残留分析法
本地全文：下载
作者：関田寛 ; 武田明治 ; 斎藤行生等
期刊名称：Journal of Health Science
印刷版ISSN：1344-9702
电子版ISSN：1347-5207
出版年度：1982
卷号：28
期号：4
页码：219-227
DOI：10.1248/jhs1956.28.4_219
出版社：The Pharmaceutical Society of Japan
摘要：The analytical method for multi-residues of chlorinated phenoxy agricultural chemicals (2, 4-D, 2, 4, 5-T and 2, 4, 5-TP) in several kinds of fruits and vegetables was investigated. These compounds could be analyzed by gas chromatography with ECD (ECD-GC) after methylation of the sample extract with diazomethane followed by clean-up on silica gel column. The minimum detectable residues of 2, 4-D, 2, 4, 5-T and 2, 4, 5-TP in fruits and vegetables (e.g. apple, egg apple, lemon and tomato) by ECD-GC were 0.005 ppm, 0.001 ppm and 0.0005 ppm, respectively. 2, 4-D separated from a lemon sample was methylated with diazomethane and confirmed by comparing the mass spectrnm and mass chromatograms obtained by GC-MS with those of the methyl ester of the authentic sample. Furthermore, in the surveillance of 2, 4-D residues in the citrus fruits imported from U.S.A. in 1979 to 1981, 2, 4-D was never detected in all of grapefruit and navel orange samples, but it was detected at the levels of 0.010 to 0.21 ppm in all of lemon samples.
关键词：pesticide residue;chlorinated phenoxy agricultural chemical;2, 4-D (2, 4-dichlorophenoxyacetic acid);2, 4, 5-T (2, 4, 5-trichlorophenoxyacetic acid);2, 4, 5-TP [2-(2, 4, 5-trichlorophenoxy) propionic acid];plant growth regulator;multi-residue analysis;gas chromatography, ECD (ECD-GC);gas chromatography-mass spectrometry (GC-MS)