文章基本信息

标题：Studies on Quinols. III. Rearrangements of 2-Oxo-8, 10-dihydroxy-△1, 9;3, 4-hexahydronaphthy1-7-acetic Acid Lactone
本地全文：下载
作者：Tsutomu Momose ; Takuichi Miki ; Kei Sawada 等
期刊名称：Chemical and Pharmaceutical Bulletin
印刷版ISSN：0009-2363
电子版ISSN：1347-5223
出版年度：1955
卷号：3
期号：5
页码：325-328
DOI：10.1248/cpb1953.3.325
出版社：The Pharmaceutical Society of Japan
摘要：2-Oxo-8, 10-dihydroxy-△^{1, 9;3, 4}-hexahydronaphthy1-7-acetic acid lactone underwent rearrangement to 2, 4, 8- and 1, 4, 8-trihydroxytetrahydronaphthy1-7-acetic acid lactone by dilute sulfuric acid, and to 2, 4-diacetoxy-8-hydroxytetrahydronaphthy1-7-acetic acid lactone by acetic anhydride and sulfuric acid. It was concluded that when hydroquinone rearrangement was hindered a resorcinol rearrangement might take place instead of catechol rearrangement. A synthesis of 1, 4, 8-trihydroxytetrahydronaphthty1-7-acetic acid lactone was also described.