文章基本信息

标题：塩素系農薬とポリ塩化ビフェニルの逆相分配薄層クロマトグラフィー
本地全文：下载
作者：竹下隆三 ; 山下多恵子
期刊名称：Journal of Health Science
印刷版ISSN：1344-9702
电子版ISSN：1347-5207
出版年度：1972
卷号：18
期号：6
页码：388-392
DOI：10.1248/jhs1956.18.388
出版社：The Pharmaceutical Society of Japan
摘要：Chromatographic patterns of chlorinated pesticides (DDT, DDE, Aldrin, Dieldrin, and Endrin), and polychlorinated biphenyls (PCBs ; Kanechlor 200-600, and decachlorobiphenyl) obtained by reversedphase partition thin-layer chromatography (TLC) were compared with those obtained by adsorption thinlayer chromatography. The compounds were separated with two TLC systems ; liquid paraffin-silica gel/methanol-water and silica gel/hexane, and visualized on the layers by silver nitrate-UV irradiation. The pesticides were separated as sharp spots on either of liquid paraffin-silica gel and silica gel layers. The chromatographic patterns of the pesticides and PCBs on the former layers contrasted in Rf values with those on the letter layers. Only on the liquid paraffin layers, each Kanechlor was observed as slightly overlapped spots, more or less than 10, and the distribution of a polychlorinated biphenyl on the layer was dependent on the chlorine content in the individual components constituting the biphenyl. Thin-layer chromatography of both the pesticides and PCBs is useful for the confirmation of results obtained by gas-liquid chromatography.