文章基本信息

标题：リノール酸メチルの通気酸化と酸化防止剤の影響(第4報)α-トコフエロールの酸化防止作用と有機酸類のSynergismについて
本地全文：下载
作者：松本茂 ; 奥本千代美 ; 加賀あき子等
期刊名称：Journal of Health Science
印刷版ISSN：1344-9702
电子版ISSN：1347-5207
出版年度：1973
卷号：19
期号：1
页码：29-34
DOI：10.1248/jhs1956.19.29
出版社：The Pharmaceutical Society of Japan
摘要：In a series of the studies, the antioxidant effect of D, L-α-tocopherol and the synergistic effects of some kinds of organic acids on the oxidation of methyl linoleate (ML) with oxygen were reported in this paper. Samples and experimental conditions were same as those described in the previous paper. Oxygen was passed through purified ML with or without the antioxidant and the synergists, then the samples obtained were estimated for peroxide value. Antioxidant effect of α-tocopherol on the oxidation at 105°was shown little in the absence of the synergist, but was remarkable in the presence of ascorbic acid or citric acid. The effect of α-tocopherol on the oxidation at 70°was clearly observed even without any synergist, but the addition of it increased markedly the antioxidant offect of α-tocopherol. The effect of α-tocopherol was compared with that of butyl hydroxy anisol (BHA), which had been reported in the previous paper. It was shown that the effect of BHA was more active than that of α-tocopherol ; even a half equivalent of BHA was more effective than α-tocopherol on the oxidation at 70°. Sixteen kinds of organic acids and esters were examined for the synergistic effect with α-tocopherol and eight of them were found to be effective in preventing oxidatien of methyl linoleate ; D, L-malic, L-tartaric, oxaloacetic, malonic, citric, L-ascorbic, and D, L-gliceric acids and diethyl malate were effective ; succinic (weak +), tartronic, propionic, lactic, β-hydroxybutyric, and pyruvic acids, gluconolactone, and triethyl citrate were ineffective. The mechanism of the synergistic action of these organic acids seemed to be complicated, but the synergist was assumed to act as a hydrogen donor to α-tocopherol (or its oxidation products).