文章基本信息

标题：輸入靴クリーム中の有機水銀化合物
本地全文：下载
作者：小嶋茂雄 ; 中村晃忠 ; 鹿庭正昭等
期刊名称：Journal of Health Science
印刷版ISSN：1344-9702
电子版ISSN：1347-5207
出版年度：1980
卷号：26
期号：1
页码：8-15
DOI：10.1248/jhs1956.26.8
出版社：The Pharmaceutical Society of Japan
摘要：Although consumer products containing organomercuric compounds have been banned in Japan since 1975, two kinds of organomercuric compounds were detected in imported shoe colors and shoe polishes, manufactured by Dylon International Ltd. in England and Kiwi Polish Co. in USA, respectively. The Dylon's compound was identified as phenylmercury by gas chromatography with electron capture detector. The Kiwi's compound was purified as the dithizonate by column and thin-layer chromatography, and its mass, proton magnetic resonance, and infrared absorption spectra were compared with those of the dithizonates of authentic organomercuric compounds. In this manner, the Kiwi's compound was identified as (3-chloro-2-methoxypropyl) mercury, which can be easily synthesized from allyl chloride and mercuric acetate in methanol.
关键词：identification;phenylmercury;(3-chloro-2-methoxypropyl) mercury;shoe colors;shoe polishes;gas chromatography;dithizonate;thin-layer chromatography;mass spectrometry;^1H-NMR spectroscopy