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  • 标题:Studies on Photochemical Reactions of Air Pollutants. XII. Photochemical Epoxidation of Aldrin with Suspended Particulates in Air
  • 本地全文:下载
  • 作者:Kazuhiro NOJIMA ; Chiho ISOGAMI ; Hisaaki ITOH
  • 期刊名称:Biological and Pharmaceutical Bulletin
  • 印刷版ISSN:0918-6158
  • 电子版ISSN:1347-5215
  • 出版年度:1994
  • 卷号:17
  • 期号:6
  • 页码:815-818
  • DOI:10.1248/bpb.17.815
  • 出版社:The Pharmaceutical Society of Japan
  • 摘要:Suspended particulates collected in Yokohama, Japan over various 24-h periods were found to cause the photochemical epoxidation of aldrin to dieldrin in good yield. trans-Stilbene did not undergo the epoxidation. Upon irradiation of aldrin together with the suspended particulates in quasi-air consisting of 18O2. 100% incorporation of 18O into dieldrin was obtained. Thus, the oxygen atom in dieldrin originated not from the particulates, but from oxygen in air.
  • 关键词:suspended particulate;vehicular exhaust gas;photochemical epoxidation;aldrin;dieldrin;metal oxide
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