文章基本信息

标题：Nanoparticle amount, and not size, determines chain alignment and nonlinear hardening in polymer nanocomposites
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作者：H. Samet Varol ; Fanlong Meng ; Babak Hosseinkhani 等
期刊名称：Proceedings of the National Academy of Sciences
印刷版ISSN：0027-8424
电子版ISSN：1091-6490
出版年度：2017
卷号：114
期号：16
页码：E3170-E3177
DOI：10.1073/pnas.1617069114
语种：English
出版社：The National Academy of Sciences of the United States of America
摘要：Polymer nanocomposites—materials in which a polymer matrix is blended with nanoparticles (or fillers)—strengthen under sufficiently large strains. Such strain hardening is critical to their function, especially for materials that bear large cyclic loads such as car tires or bearing sealants. Although the reinforcement (i.e., the increase in the linear elasticity) by the addition of filler particles is phenomenologically understood, considerably less is known about strain hardening (the nonlinear elasticity). Here, we elucidate the molecular origin of strain hardening using uniaxial tensile loading, microspectroscopy of polymer chain alignment, and theory. The strain-hardening behavior and chain alignment are found to depend on the volume fraction, but not on the size of nanofillers. This contrasts with reinforcement, which depends on both volume fraction and size of nanofillers, potentially allowing linear and nonlinear elasticity of nanocomposites to be tuned independently.
关键词：nanocomposites ; nonlinear elasticity ; strain stiffening ; polymer bridging ; polymer chain alignment