文章基本信息

标题：Metal-Organic Framework as Catalyst in Esterification of Oleic Acid for Biodiesel Production
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作者：Kui Zhou ; Somboon Chaemchuen
期刊名称：International Journal of Environmental Science and Development
印刷版ISSN：2010-0264
出版年度：2017
卷号：8
期号：4
页码：251-254
DOI：10.18178/ijesd.2017.8.4.957
摘要：Abstract Applying metal-organic frameworks (MOFs) as a solid catalyst in esterification of oleic acid and methanol for model of biodiesel production were investigated. Taking an advantage on high surface area, chemical/thermal stability and surface chemistry (acid/basicity) properties on MOF materials (MOF-808, ZIF-8, MIL-125) applied for catalyzed reaction of carboxylic acid to ester compound. Those MOF materials showed the catalytic properties higher than the reported alumina compound at same reaction condition. Their recyclability properties in heterogeneous catalyst were investigated. The characteristic properties of MOF materials such as crystal structure, porosity, surface area and functional group (chemical bonding) on spend catalyst after reaction were studied on this work. .
关键词：Metal; organic frameworks; biodiesel; esterification; heterogeneous catalyst