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标题：Characterization and synthesis of mono- and diphytanyl ethers of glycerol
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作者：C. N. Joo ; T. Shier ; M. Kates 等
期刊名称：JLR Papers In Press
印刷版ISSN：0022-2275
电子版ISSN：1539-7262
出版年度：1968
卷号：9
期号：6
页码：782-788
语种：English
出版社：American Society for Biochemistry and Molecular Biology
摘要：The methanolyzed lipids of the extreme halophile, Halobacterium cutirubrum , were separated into glycerol diether and glycerol monoether fractions. The diether was shown by synthesis to be 2,3-di- O -(3′ R ,7′ R ,ll′ R ,15′-tetramethylhexadecyl)- sn -glycerol. The monoether fraction was separated by thin-layer chromatography on boric acid-impregnated silicic acid into about equal amounts of α- and β- isomers. The α-isomer was found to be identical with the synthetic 3- O -(3′ R ,7′ R ,ll′ R ,15′-tetramethylhexadecyl)- sn -glycerol, and the β-isomer was identical with the synthetic 2- O -(3′ R ,7′ R ,11′ R ,15′-tetramethylhexadecy1) glycerol.
关键词：bacterial lipids halophilic bacteria