文章基本信息

标题：Sterol synthesis. Chemical synthesis of 5 alpha-cholest-7-en-3 beta, 14 alpha-diol.
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作者：R A Pascal ; G J Schroepfer
期刊名称：JLR Papers In Press
印刷版ISSN：0022-2275
电子版ISSN：1539-7262
出版年度：1980
卷号：21
期号：1
页码：118-122
语种：English
出版社：American Society for Biochemistry and Molecular Biology
摘要：Reported herein is the chemical synthesis of 5 alpha-cholest-7-en-3 beta, 14 alpha-diol by mild Wolff-Kishner reduction of 3 beta-acetoxy-8 alpha, 14 alpha-epoxy-5 alpha-cholestan-7-one. The preparation of 5 alpha-cholest-7-en-14 alpha-ol-3-one from 5 alpha is also described. These compounds were fully characterized by the results of infrared, nuclear magnetic resonance, and high and low resolution mass spectral studies.