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  • 标题:Occurrence of squalene, di- and tetrahydrosqualenes, and vitamin MK8 in an extremely halophilic bacterium, Halobacterium cutirubrum
  • 本地全文:下载
  • 作者:T. G. Tornabene ; M. Kates ; E. Gelpi
  • 期刊名称:JLR Papers In Press
  • 印刷版ISSN:0022-2275
  • 电子版ISSN:1539-7262
  • 出版年度:1969
  • 卷号:10
  • 期号:3
  • 页码:294-303
  • 语种:English
  • 出版社:American Society for Biochemistry and Molecular Biology
  • 摘要:The nonpolar (acetone-soluble) lipids of the extremely halophilic bacterium, Halobacterium cutirubrum , were found to consist of red carotenoid pigments (43%) and squalenes (48%) with a small amount of a vitamin K-type quinone. The squalenes were shown by n.m.r. and mass spectra to consist of the fully isoprenoid squalene (S; C30H50), dihydrosqualene (S2; C30H52), and tetrahydrosqualene (S4; C30H54) in the ratio of 1.0:0.4:0.1. S2 probably has one reduced internal isoprenoid group, and S4 has one internal and one terminal reduced isoprenyl group. The vitamin K-type quinone was shown by n.m.r. and mass spectra to have a C40 isoprenoid side chain, and is thus identified as menaquinone-8 (MK-8).
  • 关键词:menaquinone-8 ; halophilic bacteria
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