出版社:American Society for Biochemistry and Molecular Biology
摘要:The nonpolar (acetone-soluble) lipids of the extremely halophilic bacterium, Halobacterium cutirubrum , were found to consist of red carotenoid pigments (43%) and squalenes (48%) with a small amount of a vitamin K-type quinone. The squalenes were shown by n.m.r. and mass spectra to consist of the fully isoprenoid squalene (S; C30H50), dihydrosqualene (S2; C30H52), and tetrahydrosqualene (S4; C30H54) in the ratio of 1.0:0.4:0.1. S2 probably has one reduced internal isoprenoid group, and S4 has one internal and one terminal reduced isoprenyl group. The vitamin K-type quinone was shown by n.m.r. and mass spectra to have a C40 isoprenoid side chain, and is thus identified as menaquinone-8 (MK-8).