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  • 标题:Filter Paper Salt Bridge in Potentiometric Titrations: An Undergraduate Laboratory Chemical Education Article
  • 本地全文:下载
  • 作者:G. Mallika Devi ; D. A. Padmavathi ; R. Sanjeev
  • 期刊名称:World Journal of Chemical Education
  • 印刷版ISSN:2375-1665
  • 电子版ISSN:2375-1657
  • 出版年度:2016
  • 卷号:4
  • 期号:6
  • 页码:117-123
  • DOI:10.12691/wjce-4-6-1
  • 出版社:Science and Education Publishing
  • 摘要:It is essential in an electrochemistry laboratory to use salt bridge in electrochemical cells while measuring the emf. This provides a means of eliminating “liquid junction potential” between two half cells. It was indicated laconically without any experimental details (https://en.wikipedia.org/wiki/Salt_bridge#cite_ref-1) that the salt bridges can also be made using laboratory filter paper soaking in a suitable inert salt solution. In this article we have made a detailed potentiometric experimental study on four representative titrations viz. strong acid (HCl) versus strong base (NaOH), weak acid (CH3COOH) versus strong base (NaOH), ferrous iron (Fe2+) versus dichromate (Cr2O72-), and chloride ion (Cl-) versus silver ion (Ag+) using filter paper salt bridge and compared the results with those obtained using Agar-Agar salt bridge.
  • 关键词:salt bridge; Filter paper salt bridge; Potentionmetric titrations
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