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  • 标题:EFECTUL STIMULATOR AL TRIS -b-AMINOETILAŢILOR DE COBALT(III) ASUPRA PRODUCTIVITĂŢII CIANOBACTERIEI SPIRULINA PLATENSIS
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  • 作者:Aliona COTOVAIA ; Aurelian GULEA ; Sergiu ŞOVA
  • 期刊名称:Studia Universitatis Moldaviae: Stiinte Sociale
  • 印刷版ISSN:1814-3199
  • 电子版ISSN:2345-1017
  • 出版年度:2008
  • 卷号:2
  • 期号:12
  • 页码:156-163
  • 出版社:Moldova State University
  • 摘要:As a result of cobalt (III) β-aminoethylate protonation reactions with sulfuric and nitric acids, several new coordinationcompounds of composition [Co(Hetm)3](NO3)3 (1) and [Co(Hetm)3]2(SO4)3⋅4H2O (2) have been synthesized. The reactionbetween β-aminoethanol and cobalt(III) nitrate, acetate and sulfate in neutral or slightly basic alcoholic media leads tothe formation of cobalt (III) coordination compounds, which internal sphere includes both molecules of neutral β-aminoethanol(Hetm) and ions of its deprotonated form (etm). The general formula of the complexes can be given as[Co(Hetm)3][Co(etm)3]X3⋅nH2O, where X = NO3- (3), CH3COO- (4), 1/2SO42- (5); n = 0, 7, or 3 correspondingly. Thebiologic activity study of the synthesized complexes revealed that the algae biomass obtained in the nutritive media,containing coordination compounds, depends on the internal coordination sphere of the cobalt compound.
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