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  • 标题:Physico-Chemical Characterization and Biological Screening of Cyanex 302 complexes
  • 其他标题:Physico-Chemical Characterization and Biological Screening of Cyanex 302 complexes
  • 本地全文:下载
  • 作者:T. K. Pal ; M. A. Alam ; M. A. A. A. A. Islam
  • 期刊名称:Journal of Scientific Research
  • 印刷版ISSN:2070-0237
  • 电子版ISSN:2070-0245
  • 出版年度:2012
  • 卷号:4
  • 期号:2
  • 页码:427
  • DOI:10.3329/jsr.v4i2.9366
  • 语种:English
  • 出版社:Rajshahi University
  • 摘要:Several new complexes of Cr(III), Mn(II), Fe(II), Co(II) and Cu(II) containing Cyanex 302 [bis(2,4,4-trimethylpentyl) monothiophosphinic acid] were synthesized and characterized by elemental analysis, molar conductance, molecular mass determination, magnetic, UV-Visible and IR studies. The prepared metal complexes has the compositions: 2. [CrL3].H2O, 3. K[MnL3].H2O, 4. [FeL2].H2O, 5. K[CoL3] and 6. K[CuL3].H2O (Where, L means anion of bis(2,4,4-trimethylpentyl) monothiophosphinic acid). The complexes 2, 3, 5 and 6 are assumed to have octahedral geometries, but the complex 4 is tetrahedral based on experimental data. From magnetic measurements all the complexes are found to be paramagnetic. Measured molar conductance showed that the complexes 2 and 4 are non-electrolytes and complexes 3, 5 and 6 are electrolytes. Besides, some metal complexes have shown very good antibacterial and antifungal activities.Keywords: Bis(2,4,4-trimethylpentyl) monothiophosphinic acid; Biological activity.© 2012 JSR Publications. ISSN: 2070-0237 (Print); 2070-0245 (Online). All rights reserved.doi: http://dx.doi.org/10.3329/jsr.v4i2.9366 J. Sci. Res. 4 (2), 427-435 (2012)
  • 关键词:Chemistry;Bis(2;4;4-trimethylpentyl) monothiophosphinic acid; Biological activity.
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