文章基本信息
- 标题:Physico-Chemical Characterization and Biological Screening of Cyanex 302 complexes
- 其他标题:Physico-Chemical Characterization and Biological Screening of Cyanex 302 complexes
- 本地全文:下载
- 作者:T. K. Pal ; M. A. Alam ; M. A. A. A. A. Islam 等
- 期刊名称:Journal of Scientific Research
- 印刷版ISSN:2070-0237
- 电子版ISSN:2070-0245
- 出版年度:2012
- 卷号:4
- 期号:2
- 页码:427
- DOI:10.3329/jsr.v4i2.9366
- 语种:English
- 出版社:Rajshahi University
- 摘要:Several new complexes of Cr(III), Mn(II), Fe(II), Co(II) and Cu(II) containing Cyanex 302 [bis(2,4,4-trimethylpentyl) monothiophosphinic acid] were synthesized and characterized by elemental analysis, molar conductance, molecular mass determination, magnetic, UV-Visible and IR studies. The prepared metal complexes has the compositions: 2. [CrL3].H2O, 3. K[MnL3].H2O, 4. [FeL2].H2O, 5. K[CoL3] and 6. K[CuL3].H2O (Where, L means anion of bis(2,4,4-trimethylpentyl) monothiophosphinic acid). The complexes 2, 3, 5 and 6 are assumed to have octahedral geometries, but the complex 4 is tetrahedral based on experimental data. From magnetic measurements all the complexes are found to be paramagnetic. Measured molar conductance showed that the complexes 2 and 4 are non-electrolytes and complexes 3, 5 and 6 are electrolytes. Besides, some metal complexes have shown very good antibacterial and antifungal activities.Keywords: Bis(2,4,4-trimethylpentyl) monothiophosphinic acid; Biological activity.© 2012 JSR Publications. ISSN: 2070-0237 (Print); 2070-0245 (Online). All rights reserved.doi: http://dx.doi.org/10.3329/jsr.v4i2.9366 J. Sci. Res. 4 (2), 427-435 (2012)
- 关键词:Chemistry;Bis(2;4;4-trimethylpentyl) monothiophosphinic acid; Biological activity.