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标题：KINETICS OF OXIDATION OF SCHIFF BASE BY CHLORAMINE –T CATALYSED BY MIXTURE OF Os ( VIII) AND Ru (III)
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作者：R.Kalpana Devi ; G.Mathubala
期刊名称：International Journal of Innovative Research in Science, Engineering and Technology
印刷版ISSN：2347-6710
电子版ISSN：2319-8753
出版年度：2014
卷号：3
期号：11
页码：17374
DOI：10.15680/IJIRSET.2015.0311108
出版社：S&S Publications
摘要：The effect of various meta and para -substituted anils on the reaction rate had been studied at fourdifferent temperatures viz., 35 , 40 , 45 and 50 0 c and the thermodynamic parameters are also calculated. The analysisof rate constants of Ortho substituents reveals that the localized and delocalized effects are major components whileSteric effect place only the minor role. In this paper we have studied kinetics of oxidation of Schiff base byChloramine – T catalysed by mixture of Os ( VIII) and Ru (III).
关键词：Chloramine – T ; catalysed ; mixture of Os ( VIII) and Ru (III) ; Schiff base