文章基本信息

标题：Oxidation Kinetics of D-Ribose by µ- Peroxo Complex in Aqueous Medium
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作者：S. Ignatius Arockiam ; A. Peter Pascal Regis
期刊名称：International Journal of Innovative Research in Science, Engineering and Technology
印刷版ISSN：2347-6710
电子版ISSN：2319-8753
出版年度：2014
卷号：3
期号：9
页码：15931
DOI：10.15680/IJIRSET.2014.0309020
出版社：S&S Publications
摘要：A solution route method was carried out for the synthesize of μ-peroxo-bis [aminebis (ethylenediamine)cobalt(III) ]perchlorate dihydrate. FT-IR and Electronic spectroscopic methods were used to characterize the synthesizedcomplex. Biomimic oxidation of D-ribose by μ-peroxo complex has been studied kinetically in aqueous medium. Pseudofirst order conditions has been followed to determine the rate of the reaction. The Oxidation reaction shows first orderkinetics with respect to peroxo complex concentration and hydrogen ion concentration. The reaction rate points tonegligible effect on increasing ionic strength. Potentiometric method was used to carry out the biomimic oxidation of thecomplex μ-peroxo complex. Thermodynamic and Arrhenius parameters were calculated and a plausible mechanism hasbeen proposed.
关键词：Kinetics; Oxidation; peroxo complex; D-ribose; Activation parameters