文章基本信息

标题：Theroritical Investigating Role of Heavy Metals in Ionic Liquids Catalysts Function for Polyhydroquinolines Synthesis Reactions
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作者：Sayed Ali Ahmadi ; Razieh Razavi ; Mohammad Mehdi Foroghi 等
期刊名称：International Journal of Innovative Research in Science, Engineering and Technology
印刷版ISSN：2347-6710
电子版ISSN：2319-8753
出版年度：2015
卷号：4
期号：9
页码：9377
DOI：10.15680/IJIRSET.2015.0409151
出版社：S&S Publications
摘要：Polyhydroquinolines and its derivatives are an important group of organic Heterocyclic compounds. Dueto their applications in pharmaceuticaland chemicalindustries, study of new methods of synthesis is considerablysubstantial. One of such synthesis methods is the Hantzsch reaction in which numerous factors are used to increase thereaction efficiency. The most critical component includes heterogeneous and reusable catalyst. Therefore, in order tohave higher efficiency in shorter time for polyhydroquinolines synthesis using the heterogeneous and reusable catalystsinside ionic liquids, we performed a study on function of different ionic liquids. The test uses B3LYP/6-31goptimization method for polyhydroquinolines synthesis with aromaticaldehyde,dimedone,ethyl acetateand ammoniumacetate in the presence of catalyst.
关键词：ionic liquids; DFT; hydroquinoline; Hantzsch reaction