文章基本信息

标题：Thermodynamic Study of Polyhydroquinoline Synthesis in the Presence of the Catalyst in Ionic Liquid
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作者：Reza Ghahremani ; Dadkhoda Ghazanfari ; Razieh Razavi 等
期刊名称：International Journal of Innovative Research in Science, Engineering and Technology
印刷版ISSN：2347-6710
电子版ISSN：2319-8753
出版年度：2015
卷号：4
期号：9
页码：9276
DOI：10.15680/IJIRSET.2015.0409146
出版社：S&S Publications
摘要：Polyhydroquinolines and its derivatives are an important group of organic Heterocyclic compounds.Due to their applications in pharmaceuticaland chemicalindustries, study of new methods of synthesis is considerablysubstantial. One of such synthesis methods is the Hantzsch reaction in which numerous factors are used to increase thereaction efficiency. The most critical component includes heterogeneous and reusable catalyst. Therefore, in order tohave higher efficiency in shorter time for polyhydroquinolines synthesis using the heterogeneous and reusable catalystsinside ionic liquids, we performed a study on function of different ionic liquids. The test uses B3LYP/6-31goptimization method for polyhydroquinolines synthesis with aromaticaldehyde, dimedone, ethyl acetate andammonium acetate in the presence of catalyst.
关键词：ionic liquids; DFT; hydroquinoline; Hantzsch reaction