文章基本信息

标题：Kinetics of Os (VIII ) Catalysed Oxidation of Benzaldehyde Anils by PDC
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作者：Dr.V.Krishnasamy ; G.Mathubala
期刊名称：International Journal of Innovative Research in Science, Engineering and Technology
印刷版ISSN：2347-6710
电子版ISSN：2319-8753
出版年度：2015
卷号：4
期号：9
页码：8995
DOI：10.15680/IJIRSET.2015.0409219
出版社：S&S Publications
摘要：The effect of various meta and para -substituted anils on the reaction rate had been studied at fourdifferent temperatures viz., 35 , 40 , 45 and 50 0 c and the thermodynamic parameters are also calculated. The analysisof rate constants of ortho substituents reveals that the localized and delocalized effects are major components whilesteric effect place only the minor role. In this paper we have studied the kinetics of OS(VIII ) catalysed oxidation ofbenzaldehyde anils by PDC
关键词：PDC ; parasubstituted ; delocalized and components