文章基本信息

标题：Os (Viii) Catalysed Oxidation of Schiff Base By Chloramine – T In Aqueous Acetic Acid Medium – Kinetic Study
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作者：G.Mathubala ; R.Kalpana Devi
期刊名称：International Journal of Innovative Research in Science, Engineering and Technology
印刷版ISSN：2347-6710
电子版ISSN：2319-8753
出版年度：2015
卷号：4
期号：6
页码：4203
DOI：10.15680/IJIRSET.2015.0406231
出版社：S&S Publications
摘要：The effect of various meta and para -substituted anils on the reaction rate had been studied at four different temperatures viz., 35 , 40 , 45 and 50 0 c and the thermodynamic parameters are also calculated. The analysis of rate constants of Ortho substituents reveals that the localized and delocalized effects are major components while Steric effect place only the minor role. In this paper we have studied OS ( VIII) catalysed oxidation of SCHIFF base by Chloramine – T in aqueous acetic acid medium – kinetic study
关键词：Steric effect ; meta and para -substituted ; Ortho substituents ; minor role