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  • 标题:X線結晶学的研究による写真用色素の低次元凝集体の構造モデル
  • 本地全文:下载
  • 作者:中津 和三 ; 吉岡 寛 ; 西垣 敏
  • 期刊名称:日本写真学会誌
  • 印刷版ISSN:0369-5662
  • 电子版ISSN:1884-5932
  • 出版年度:1983
  • 卷号:46
  • 期号:2
  • 页码:89-98
  • DOI:10.11454/photogrst1964.46.89
  • 出版社:The Society of Photographic Science and Technolgy of Japan
  • 摘要:

    In order to obtain reliable structural models of molecular arrangements in low-dimensional dye aggregates, crystal structures of nineteen cyanines, four merocyanines, eight styryls, and six TCNQ salts of cyanines have been investigated by X-ray crystallography. In most of the crystals the dye molecules stack face-to-face to form columns or one-dimensional arrays; they were classified into five distinctive types according mainly to the disposition of inversion center that relates the adjacent dye molecules; this confines the magnitudes of the columnar and the nearest-neighbor slip-angles. The columns assemble together to form layer-like or two-dimensional arrangements which resemble those so far proposed. All the four patterns, herring-bone, brickwork, staircase, and ladder, found in the crystal structures, were displayed and discussed. An attempt to correlate the molecular shape with the aggregation type is given.

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