首页    期刊浏览 2024年12月03日 星期二
登录注册

文章基本信息

  • 标题:EDTA-Fe (III) を含む色素溶液の光退色反応 (I)
  • 本地全文:下载
  • 作者:石川 和夫 ; 白井 靖男 ; 山崎 秀行
  • 期刊名称:日本写真学会誌
  • 印刷版ISSN:0369-5662
  • 电子版ISSN:1884-5932
  • 出版年度:1977
  • 卷号:40
  • 期号:3
  • 页码:122-129
  • DOI:10.11454/photogrst1964.40.122
  • 出版社:The Society of Photographic Science and Technolgy of Japan
  • 摘要:

    The light fading reaction of 3-Methyl-1-phenyl-4-( p -diethylaminophenyl) imino-2-pyrazoline-5-one and 2-Acetamido-N-(4-dithylaminophenyl) benzoquinone monoimine in the solution containing EDTA-Fe (III) has been investigated. The light fading reaction of those dyes is remarkably accelerated by the presence of small amount of EDTA-Fe (III). The rate of the light fading reaction shows a significant dependence upon pH value of the solution and concentration of EDTA-Fe (III). It is concluded that an initiation step of the light fading reaction is due to the photoreduction from EDTA-Fe (III) to EDTA-Fe (II). The light fading reaction in a pH value of 5.4 may be expressed as follows: EDTA-Fe (III) hυ →EDTA-Fe (II) Dye+nEDTA-Fe (II) +nH+→HnDye (leuco dye) +nEDTA-Fe (III)

国家哲学社会科学文献中心版权所有