文章基本信息

标题：し尿処理場排水中における無機水銀の光化学的アルキル化
本地全文：下载
作者：田中克彦 ; 深谷勝久 ; 和田裕等
期刊名称：Journal of Health Science
印刷版ISSN：1344-9702
电子版ISSN：1347-5207
出版年度：1978
卷号：24
期号：4
页码：194-199
DOI：10.1248/jhs1956.24.194
出版社：The Pharmaceutical Society of Japan
摘要：Inorganic mercury (HgCl₂) in activated sludge, sewage, urine, and aqueous extract of feces was alkylated under irradiation. A considerable amount of alkylmercury was formed by irradiation of inorganic mercury solution containing acetic acid or propionic acid in the presence of ammonia but only a small amount of alkylmercury formed in the absence of ammonia. This fact suggests that aminomercuric chloride (HgNH₂Cl), formed by the reaction of mercuric chloride with ammonia, accelerated the photochemical alkylation of inorganic mercury. It was also found that creatinine, which was contained in sewage and urine, showed a photochemical alkylating ability but creatine, the open form of lactam ring of creatinine, did not show such ability.
关键词：sewage;mercuric chloride;alkylation;methylmercury;ethylmercury;acetic acid;propionic acid;ammonia;aminomercuric chloride;creatinine