文章基本信息

标题：Microwave-assisted Synthesis of Greigite Fe3S4 nanosheets wrapped in an rGO Matrix as anode material for Sodium-ion batteries
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作者：Ikhwan Choi ; Bolin Liu ; Youqi Zhu 等
期刊名称：MATEC Web of Conferences
电子版ISSN：2261-236X
出版年度：2022
卷号：358
页码：1-5
DOI：10.1051/matecconf/202235801068
语种：English
出版社：EDP Sciences
摘要：Greigite (Fe3S4), which have ferromagnetic in inverse thiospinel (AB2S4), is widely researched to use an adsorbent and biomedical field because non-toxicity and abundant in nature. Iron-based materials are known to have a high theoretical capacity because of their multivalent state including redox pairs, but still suffer from collapse and aggregate during the charge/discharge process. Here, the synthesized Fe3S4 nanosheet structure materials wrapped with reduced graphene oxide (Fe3S4NSs@rGO) were used as an anode electrode material for sodium-ion batteries (SIBs). The nano-sheet structure facilitates ion diffusion through expanded surface area, and rGO can effectively improve electrochemical conductivity and structure stability. As-prepared Fe3S4NSs@rGO were used as a host material to insert Na-ion via a conversion process, and the stabilized structure maintains the high capacity and long cycle performance. Thus, the Fe3S4NSs@rGO deliver a reversible capacity of 950 mAh g−1 after 200 cycles at a current density of 1A g−1 and 524 mAh g−1 after 400 cycles at a current density of 2A g−1, which is much higher than reported materials.