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标题：Free radical formation from sonolysis of water in the presence of different gases
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作者：Masahiro Kohno ; Takayuki Mokudai ; Toshihiko Ozawa 等
期刊名称：Journal of Clinical Biochemistry and Nutrition
印刷版ISSN：0912-0009
电子版ISSN：1880-5086
出版年度：2011
卷号：49
期号：2
页码：96-101
DOI：10.3164/jcbn.10-130
出版社：The Society for Free Radical Research Japan
摘要：In the present study by applying electron spin resonance-spin trapping method, when a high frequency (1650 kHz) ultrasound was irradiated to water dissolved with different gas molecules (O₂, N₂, Ar, Ne, He, and H₂) at 25°C of water bulk temperature, free radical generation pattern differed dependently on the dissolved gas molecules. Only ^•OH was detected in the O₂-dissolved water sample, and the amount of the radical was much greater than that determined in any of other gas-dissolved water samples. One of the possible reasons to explain why the ^•H radical was not detected in the O₂-dissolved water is that the ^•H reacts with O₂ to form ^•OOH. However, no electron spin resonance signals related to the adduct of not only 5,5-dimethyl-1-pyrroline-N-oxide but 5-(2,2-Dimethyl-1,3-propoxy cyclophosphoryl)-5-methyl-1-pyrroline N-oxide and ^•OOH were observed. In the H₂-dissolved water, only ^•H was detected, suggesting that H₂ reduces or neutralizes ^•OH. In the N₂-disolved water, both ^•OH and ^•H were detected at comparable level. In the water samples dissolved with rare gases (Ar, Ne, and He), the amount of ^•H was almost double as compared with that of ^•OH, and both ^•OH and ^•H yields increased in the order Ar > Ne > He.
关键词：water sonolysis;radical formation;electron spin resonance