文章基本信息

标题：Study of the influence of oxidizing parameters on the composition and morphology of Al2O3•CoOx coatings on AL25 alloy
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作者：Ann Karakurkchi ; Mykola Sakhnenko ; Maryna Ved' 等
期刊名称：Eastern-European Journal of Enterprise Technologies
印刷版ISSN：1729-3774
电子版ISSN：1729-4061
出版年度：2018
卷号：2
期号：12
页码：11-19
DOI：10.15587/1729-4061.2018.128457
语种：English
出版社：PC Technology Center
摘要：The influence of operating parameters of plasma-electrolytic oxidation in diphosphate cobalt-containing electrolyte on the process of formation of oxide coatings on alumosilicon alloy AL25 (GOST 1583) was studied. It was shown that inclusion of cobalt into the composition of surface oxide layers leads to a change of morphology and topography of the surface. Variation of current density and PEO time allows flexible control of the process of incorporation of the catalytic component into the matrix of oxide of basic metal. It was shown that at an increase in oxidation time, cobalt content in the surface oxide layer increases.The rational mode of plasma-electrolytic treatment of piston alloy in diphosphate electrolyte for obtaining oxide coatings, enriched with cobalt, was substantiated. It is advisable to perform formation of PEO-coatings on AL25 with developed globular-mosaic surface, maximum cobalt content, with minimizing impurities in the range of current densities of 3–5 A/dm2 within 20–40 min. The obtained cobalt-containing oxide coatings can be used in the air and water purification systems, specifically, for intracylinder catalysis of gas emissions of internal combustion engines.
关键词：piston silumin;AL25;plasma-electrolytic oxidation;oxide coating;surface morphology