文章基本信息

标题：The study of physical-chemical patterns of resource-saving recycling of tungsten-containing ore raw materials by solid-phase reduction
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作者：Stanislav Hryhoriev ; Artem Petryshchev ; Olga Sergienko 等
期刊名称：Eastern-European Journal of Enterprise Technologies
印刷版ISSN：1729-3774
电子版ISSN：1729-4061
出版年度：2018
卷号：1
期号：12
页码：4-9
DOI：10.15587/1729-4061.2018.122743
语种：English
出版社：PC Technology Center
摘要：It was determined that the oxidic tungsten concentrate is represented basically by CaWO4. Other phases have a fragmentary manifestation with a low intensity of the corresponding diffraction peaks. Microstructure is heterogeneous, disordered. Particles with presence of the accompanying ore impurities (molybdenum, calcium, silicon, iron, aluminum, fluorine and carbon) were found. The metallized tungsten concentrate after heat treatment at 1,250 K had a reduction degree of 21 % with a prevalence of CaWO4 in the phase composition. An increase in temperature to 1,350 K and 1,450 K provided a reduction degree of 69 % and 87 %, respectively. Under these conditions, a significant predominance of WC and W2C carbides was found in the phase composition. The presence of CaWO4 was of a residual nature with a relatively low intensity of manifestation. The microstructure of metallized tungsten concentrate was inhomogeneous with the presence of particles of various sizes and chemical compositions. As the reduction temperature increased, manifestation of the processes of sintering of particles was observed, especially clearly after treatment at 1,350 K and 1,450 K.
关键词：tungsten concentrate;carbothermic reduction;metallization;sublimation;phase analysis;microstructure;resource saving