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标题：Anodic electrosynthesis of MIL-53(Al)-N(CH ₂PO ₃H ₂) ₂ as a mesoporous catalyst for synthesis of novel ( N-methyl-pyrrol)-pyrazolo[3,4- b]pyridines via a cooperative vinylogous anomeric based oxidation
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作者：Sima Kalhor ; Mahmoud Zarei ; Mohammad Ali Zolfigol 等
期刊名称：Scientific Reports
电子版ISSN：2045-2322
出版年度：2021
卷号：11
DOI：10.1038/s41598-021-97801-7
语种：English
出版社：Springer Nature
摘要：In this paper, the MIL-53(Al)-NH 2 metal–organic frameworks (MOFs) was prepared based on the anodic electrosynthesis under green conditions. The anodic electrosynthesis as an environmentally friendly procedure was performed in the aqueous solution, room temperature, atmospheric pressure, and in the short reaction time (30 min). Also, the employed procedure was accomplished without the need for the ex-situ salt and base/probase additives as cation source and ligand activating agent at the constant current mode (10.0 mA cm −2). The electrosynthesized MOFs was functionalized with phosphorus acid tags as a novel mesoporous catalyst. This mesoporous catalyst was successfully employed for synthesis of new series ( N-methyl-pyrrol)-pyrazolo[3,4- b