文章基本信息

标题：Investigating the critical characteristics of thermal runaway process for LiFePO 4/graphite batteries by a ceased segmented method
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作者：Xuan Tang ; Guangxu Zhang ; Xueyuan Wang 等
期刊名称：iScience
印刷版ISSN：2589-0042
出版年度：2021
卷号：24
期号：10
页码：1-19
DOI：10.1016/j.isci.2021.103088
语种：English
出版社：Elsevier
摘要：SummaryLithium-ion batteries (LIBs) are widely used as the energy carrier in our daily life. However, the higher energy density of LIBs results in poor safety performance. Thermal runaway (TR) is the critical problem which hinders the further application of LIBs. Clarifying the mechanism of TR evolution is beneficial to safer cell design and safety management. In this paper, liquid nitrogen spray is proved to be an effective way to stop the violent reaction of LIBs during the TR process. Based on extended-volume accelerating rate calorimetry, the liquid nitrogen ceasing combined with non-atmospheric exposure analysis is used to investigate the TR evolution about LiFePO4/graphite batteries at critical temperature. Specifically, the geometrical shape, voltage, and impedance change are monitored during the TR process on the cell level. The morphologies/constitution of electrodes and separators are presented on the component level. Utilizing the gas analysis, the failure mechanism of the prismatic LiFePO4/graphite battery is studied comprehensively.Graphical abstractDisplay OmittedHighlights•A comparative study on the thermal runaway evolution of LIBs•The gas release before venting is analyzed•The voltage shake after internal short circuit occurs is explained•The deposition/decomposition of LiPF6affects the morphology of electrodesElectrochemistry; Energy application; Energy storage