文章基本信息
- 标题：Synthesis of New Derivatives of BEDT-TTF: Installation of Alkyl, Ethynyl, and Metal-Binding Side Chains and Formation of Tris(BEDT-TTF) Systems
- 本地全文：下载
- 作者：Songjie Yang ; Matteo Zecchini ; Andrew C. Brooks 等
- 期刊名称：Maine Policy Review
- 印刷版ISSN：2312-7481
- 出版年度：2021
- 卷号：7
- 期号：8
- 页码：110
- DOI：10.3390/magnetochemistry7080110
- 语种：English
- 出版社：The University of Maine
- 摘要：The syntheses of new BEDT-TTF derivatives are described. These comprise BEDT-TTF with one ethynyl group (HC≡C-), with two (<i>n</i>-heptyl) or four (<i>n</i>-butyl) alkyl side chains, with two <i>trans</i> acetal (-CH(OMe)<sub>2</sub>) groups, with two <i>trans</i> aminomethyl (-CH<sub>2</sub>NH<sub>2</sub>) groups, and with an iminodiacetate (-CH<sub>2</sub>N(CH<sub>2</sub>CO<sub>2</sub><sup>−</sup>)<sub>2</sub> side chain. Three transition metal salts have been prepared from the latter donor, and their magnetic properties are reported. Three <i>tris</i>-donor systems are reported bearing three BEDT-TTF derivatives with ester links to a core derived from benzene-1,3,5-tricarboxylic acid. The stereochemistry and molecular structure of the donors are discussed. X-ray crystal structures of two BEDT-TTF donors are reported: one with two CH(OMe)<sub>2</sub> groups and with one a -CH<sub>2</sub>N(CH<sub>2</sub>CO<sub>2</sub>Me)<sub>2</sub> side chain.
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