文章基本信息

标题：Coking-resistant dry reforming of methane over Ni/γ-Al 2O 3 catalysts by rationally steering metal-support interaction
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作者：Bo Yang ; Jiang Deng ; Hongrui Li 等
期刊名称：iScience
印刷版ISSN：2589-0042
出版年度：2021
卷号：24
期号：7
页码：1-15
DOI：10.1016/j.isci.2021.102747
语种：English
出版社：Elsevier
摘要：SummaryThe coking issue is the main challenge for dry reforming of methane (DRM) over Ni-based catalysts. Herein, we excavate the reasons for the enhanced coking resistance of the bounded Ni over the free state Ni in Ni/γ-Al2O3catalysts for DRM. Rational metal-support interaction of the bounded Ni would facilitate desorption of CO, thus suppressing CO disproportionation and decreasing carbon deposition. The higher activity of the bounded Ni is ascribed to better methane cracking ability, stronger adsorption, and activation of CO2by forming polydentate carbonate. The better activation of CO2over the bounded Ni would also contribute to the gasification of formed coke. We gain an insight into the anti-coking mechanism of DRM determined by metal-support interaction in Ni/γ-Al2O3catalysts through mechanistic studies. It is believed that our findings would enlighten the design of more efficient catalysts for DRM.Graphical abstractDisplay OmittedHighlights•The anti-coking ability of the bounded Ni is better than the free state Ni•The bounded Ni has a stronger ability to activate CO2to produce active O∗ species•High reactivity and stable polydentate carbonate enables efficient reaction•Rational metal-support interaction results in good resistance to CO poisoningChemistry; Industrial chemistry; Inorganic chemistry; Catalysis