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  • 标题:Supramolecular exfoliation of layer silicate clay by novel cationic pillar[5]arene intercalants
  • 本地全文:下载
  • 作者:Takahiro Kakuta ; Yudai Baba ; Tada-aki Yamagishi
  • 期刊名称:Scientific Reports
  • 电子版ISSN:2045-2322
  • 出版年度:2021
  • 卷号:11
  • DOI:10.1038/s41598-021-90122-9
  • 语种:English
  • 出版社:Springer Nature
  • 摘要:Clays are multi-layered inorganic materials that can be used to prepare nanocomposite fillers. Because the multi-layered structure is thermodynamically stable, it is difficult to change a multi-layered material into single layers to improve its dispersity. Previously, clays were modified with dodecylammonium cations to promote complexation with nylon 6, nylon 66, polypropylene, polyethylene, polystyrene, and polycaprolactone to increase the mechanical strength (and/or thermal stability) of the composite material; however, complete exfoliation could not be achieved in these composites. In this study, pillar[5
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