文章基本信息

标题：Kinetics of Impurity Removal in Zinc Hydrometallurgy Based on Parameter Estimation
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作者：Qianqian Wang ; Minan Tang ; Aimin An 等
期刊名称：E3S Web of Conferences
印刷版ISSN：2267-1242
电子版ISSN：2267-1242
出版年度：2021
卷号：267
页码：1-7
DOI：10.1051/e3sconf/202126702051
语种：English
出版社：EDP Sciences
摘要：Impurity removal is a momentous part of zinc hydrometallurgy process. In this paper, a hybrid modeling method of mechanism modeling and parameter estimation modeling was proposed on the basis of not changing the actual production process of lead-zinc smeltery. Firstly, the overall nonlinear dynamic mechanism model was established, and then the deviation between the theoretical value and the actual detected outlet ion concentration was taken as the objective function to establish the parameter estimation optimization model. The gradient vector and Hessian matrix of the objective function with respect to the parameter vector were derived, and the algorithm based on the steepest descent and Newton method was given. Finally, using the production data of a lead-zinc smeltery in China, the model parameters were inversed. An intensive simulation validation and analysis of the dynamic characteristics shows the accuracy and the potential of the model, also in the perspective of practical implementation, which provides the basis for the optimal control of system output and the guidance for zinc powder addition.