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标题：Effect of different supports for copper as catalysts on glycerol hydrogenolysis to 1,2-propanediol
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作者：Norsahida Azri ; Ramli Irmawati ; Usman Idris Nda-Umar 等
期刊名称：Journal of King Saud University - Science
印刷版ISSN：1018-3647
出版年度：2021
卷号：33
期号：4
页码：1-8
DOI：10.1016/j.jksus.2021.101417
语种：English
出版社：Elsevier
摘要：Graphical abstractDisplay OmittedHighlights•Effect of different supports for copper as catalysts for glycerol hydrogenolysis to 1,2-propanediol were explored.•Existence of dispersed metallic copper species (Cu) on dolomite support, high acidity, high metal reducibility (easy reduction of copper at lower temperature) and the small Cu particle of Cu/Dol were the factor for its high glycerol hydrogenolysis performance.•Cu/Dol catalyst giving 78.5% glycerol conversion and 79% selectivity towards.•1,2-PDO at 200 °C, 4 MPa H2in 10 h reaction time.AbstractIn this work, several copper supported catalysts, Cu/Dol, Cu/Al2O3, Cu/Bent, Cu/Mont, and Cu/Talc were prepared using wet impregnation route and characterized using BET, BJH, XRD, H2-TPR, NH3–TPD, and SEM analytical techniques and subsequently tested in hydrogenolysis of glycerol to 1,2-propanediol (1,2-PDO). The nature of support was found to determine the activation of the catalysts. Among the tested catalysts, dolomite supported copper catalyst (Cu/Dol) exhibited superior performance due to the copper and dolomite species mutual interaction. The findings from the various characterization tests showed that the presence of copper species were essentially enriched on the dolomite grain surfaces, the redox properties, and acidic property of the catalyst enhanced, as well as the formation of the small size of the catalyst (Cu/Dol) contributed to the high conversion of glycerol (78.5%) and high 1,2-PDO selectivity (79%) with low methanol production as the by-product at 200 °C, 4 MPa H2and 10 h reaction conditions.
关键词：Copper;Comparison support;Acidity;1,2-PDO;Hydrogenolysis