文章基本信息

标题：Hybrid UV/COP advanced oxidation process using ZnO as a catalyst immobilized on a stone surface for degradation of acid red 18 dye
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作者：Hakimeh Mahdizadeh ; Alireza Nasiri ; Majid Amiri Gharaghani 等
期刊名称：MethodsX
印刷版ISSN：2215-0161
电子版ISSN：2215-0161
出版年度：2020
卷号：7
页码：1-10
DOI：10.1016/j.mex.2020.101118
语种：English
出版社：Elsevier
摘要：AbstractAzo dyes are the largest group of synthetic organic dyes which containing the linkage CNNC and used in various industries such as textile industries leather articles, and some foods. Azo dyes are resistant compounds against the biodegradation processes. The purpose of this research was hybrid UV/COP advanced oxidation process using ZnO as a catalyst immobilized on a stone surface for degradation of acid red 18 (AR18) Dye. In the hybrid process using some parameters such as the dye initial concentration, pH, contact time and catalyst concentration, the process efficiency was investigated. In order to the dye removal, the sole ozonation process (SOP), catalytic ozonation process (COP) and photocatalytic process (UV/ZnO) were used. The ZnO nanoparticles were characterized by XRD, SEM and TEM analyses. The maximum dye removal was achieved 97% at the dye initial concentration 25 mg/L, catalyst concentration 3 g/L, contact time 40 min and pH 5. As a real sample, the Yazdbaf textile factory wastewater was selected. After that, the physicochemical quality was evaluated. As well as, in the optimal conditions, the AR18 dye removal efficiency was achieved 65%. The kinetic results demonstrated that the degradation reaction was fitted bypseudo-first-order kinetic. The UV/COP hybrid process had high efficiency for removal of resistant dyes from the textile wastewater.Advantages of this technique were as follows:•ZnO nanoparticles were synthesized as catalyst by thermal method and were immobilized on the stones.•pH changes had no significant effect on the removal efficiency.•In the kinetic studies, the decomposition reaction followedpseudo-first order kinetic.Graphical abstractDisplay Omitted
关键词：AOP process;Dyes;ZnO;Water treatment;Textile industry