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标题：Pristine and palladium-doped perovskite bismuth ferrites and their nitrogen dioxide gas sensor studies
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作者：Shivaji D. Waghmare ; Siddheshwar D. Raut ; Balaji G. Ghule 等
期刊名称：Journal of King Saud University - Science
印刷版ISSN：1018-3647
出版年度：2020
卷号：32
期号：7
页码：3125-3130
DOI：10.1016/j.jksus.2020.08.024
语种：English
出版社：Elsevier
摘要：AbstractUndoped and palladium-doped perovskite bismuth ferrite nitrogen dioxide (NO2) gas sensors (BiFeO3i.e. BFO and Pd-BiFeO3i.e. Pd-BFO) are successfully synthesizedviaan easy and low-cost sol–gel process. The Pd-doping in BFO is confirmed through an X-ray diffraction data, field emission scanning electron microscopy images, energy-dispersive X-ray spectroscopy analysis, and its influence on the structure, morphology, surface area, and the NO2gas sensor performance of the BFO sensor has been examined and explored. Moreover, the plausible gas sensing response mechanism of Pd-BFO film sensor has also been proposed. The nanocubes embedded into a uniformly distributed upright standing nanoplates facilitate better gas adsorption and diffusion behavior on providing an excellent NO2-sensing performance with good sensitivity, excellent selectivity, better response (90 s)/recovery (110 s), and noticeable repeatability under a fixed 100 ppm NO2gas concentration level at an optimized low operating temperature i.e. 150 °C.
关键词：BiFeO;3;and Pd;-;BiFeO;3;NO;2;gas sensors;Sol–gel synthesis;Structural elucidation;Dual surface morphology