文章基本信息

标题：Discovering Biomass Structural Determinants Defining the Properties of Plant-Derived Renewable Carbon Fiber
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作者：Qiang Li ; Cheng Hu ; Mengjie Li 等
期刊名称：iScience
印刷版ISSN：2589-0042
出版年度：2020
卷号：23
期号：8
页码：1-25
DOI：10.1016/j.isci.2020.101405
语种：English
出版社：Elsevier
摘要：SummaryTraditional lignocellulosic feedstock research has focused on biomass characteristics essential for improving saccharification efficiency, yet the key biomass features underlying high-quality renewable lignin materials remain unknown. Nevertheless, modern biorefinery cannot achieve sustainability and cost-effectiveness unless the lignin stream can be valorized. We hereby addressed these scientific gaps by investigating biomass characteristics defining lignin-based carbon materials properties. Lignin from eight sorghum samples with diverse characteristics was fabricated into carbon fibers (CFs). Remarkably, only lignin uniformity was found to define CF mechanical performance, highlighting the new structure-property relationship. Contrarily, lignin content and composition did not impact on carbon material properties. Mechanistic study by XRD and Raman spectroscopy revealed that higher lignin uniformity enhanced CF microstructures, in particular, turbostratic carbon content. The study for the first time highlighted lignin uniformity as an important biomass structure determinant for renewable products, which opened up new avenues for feedstock design toward diverse products enabling sustainable and cost-effective bioeconomy.Graphical AbstractDisplay OmittedHighlights•Lignin uniformity was discovered to define biomass-derived CF mechanical property•Traditional key feedstock characteristics do not significantly impact on CF property•Feedstock variants and growth conditions impact on lignin uniformity•Novel feedstock design needs to be developed for biomaterial manufacturingPolymer Chemistry; Biomass; Materials Chemistry; Materials Property