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  • 标题:EFFECT OF COMBINED UV/CHLORINE TREATMENT ONTHE FORMATION OF DICHLORONITROMETHANE FROMDIMETHYLAMINE AND ITS PHOTODEGRADATION
  • 本地全文:下载
  • 作者:Lin Deng ; Shuang Fu ; Yang Li
  • 期刊名称:Fresenius Environmental Bulletin
  • 印刷版ISSN:1018-4619
  • 出版年度:2020
  • 卷号:29
  • 期号:9
  • 页码:7579-7588
  • 语种:English
  • 出版社:PSP Publishing
  • 摘要:The purpose of this study was to investigate the effects of dimethylamine (D M A) on the formation and degradation of dichloronitromethane (DCNM) under UV/chlorine. The impact factors were selected as D M A in itia l concentration, in itia l free chlorine concentration, U V intensity, pH and tert butyl alco­hol (TBA) to study the formation of DCNM. Under the same external conditions, the degradation of DCNM was investigated by using DCNM standard solution. The results showed that the degradation rate of DCNM increased w ith the increase of pH, U V intensity and free chlorine concentration. The degra­dation reaction of DCNM fitted the first-order kinet­ics. From the formation experiments of DCNM from DM A, the formation concentration of DCNM in­creased first and then decreased under UV/chlorine. the peak value of DCNM concentration at the sixth min increased w ith the increase of free chlorine and D M A and decreased w ith the increase of pH. The formation and degradation rate of DCNM decreased w ith the increase of TBA. Finally, the formation and degradation pathways of DCNM from D M A had been inferred under UV/chlorine. This study can pro­vide theoretical basis and technical support for the disinfection process of drinking water and sewage treatment.
  • 关键词:Dichloronitromethane;Formation and degradation;Dime­thylamine;UV/chlorine
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