文章基本信息

标题：Stereoassembled V2O5@FeOOH Hollow Architectures with Lithiation Volumetric Strain Self-Reconstruction for Lithium-Ion Storage
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作者：Yao Zhang ; Kun Rui ; Aoming Huang 等
期刊名称：Research
电子版ISSN：2639-5274
出版年度：2020
卷号：2020
页码：1-9
DOI：10.34133/2020/2360796
语种：English
出版社：American Association for the Advancement of Science
摘要：Vanadium oxides have recently attracted widespread attention due to their unique advantages and have demonstrated promising chemical and physical properties for energy storage. This work develops a mild and efficient method to stereoassemble hollow V2O5@FeOOH heterostructured nanoflowers with thin nanosheets. These dual-phased architectures possess multiple lithiation voltage plateau and well-defined heterointerfaces facilitating efficient charge transfer, mass diffusion, and self-reconstruction with volumetric strain. As a proof of concept, the resulting V2O5@FeOOH hollow nanoflowers as an anode material for lithium-ion batteries (LIBs) realize high-specific capacities, long lifespans, and superior rate capabilities, e.g., maintaining a specific capacity as high as 985 mAh g−1 at 200 mA g−1 with good cyclability.