文章基本信息

标题：A Hybrid Na//K+-Containing Electrolyte//O2 Battery with High Rechargeability and Cycle Stability
本地全文：下载
作者：Zhuo Zhu ; Xiaomeng Shi ; Dongdong Zhu 等
期刊名称：Research
电子版ISSN：2639-5274
出版年度：2019
卷号：2019
页码：1-9
DOI：10.34133/2019/6180615
语种：English
出版社：American Association for the Advancement of Science
摘要：Na-O2 and K-O2 batteries have attracted extensive attention in recent years. However, the parasitic reactions involving the discharge product of NaO2 or K anode with electrolytes and the severe Na or K dendrites plague their rechargeability and cycle stability. Herein, we report a hybrid Na//K+-containing electrolyte//O2 battery consisting of a Na anode, 1.0 M of potassium triflate in diglyme, and a porous carbon cathode. Upon discharging, KO2 is preferentially produced via oxygen reduction in the cathode with Na+ stripped from the Na anode, and reversely, the KO2 is electrochemically decomposed with Na+ plated back onto the anode. The new reaction pathway can circumvent the parasitic reactions involving instable NaO2 and active K anode, and alternatively, the good stability and conductivity of KO2 and stable Na stripping/plating in the presence of K+ enable the hybrid battery to exhibit an average discharge/charge voltage gap of 0.15 V, high Coulombic efficiency of >96%, and superior cycling stability of 120 cycles. This will pave a new pathway to promote metal-air batteries.